Finished work
4
.gitignore
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|||||||
|
.venv/
|
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|
.vscode/
|
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|
.~lock*
|
||||||
|
ОТЧЕТЫ/
|
1984
README.html
Normal file
253
README.md
@ -1,253 +0,0 @@
|
|||||||
МИНОБРНАУКИ РОССИИ
|
|
||||||
|
|
||||||
Санкт-Петербургский государственный
|
|
||||||
|
|
||||||
электротехнический университет
|
|
||||||
|
|
||||||
«ЛЭТИ» им. В.И. Ульянова (Ленина)
|
|
||||||
|
|
||||||
Кафедра Микрорадиоэлектроники и технологии радиоаппаратуры
|
|
||||||
|
|
||||||
(МИТ)
|
|
||||||
|
|
||||||
ОТЧЕТ
|
|
||||||
|
|
||||||
**по ИДЗ**
|
|
||||||
|
|
||||||
**по дисциплине «ОЭиР»**
|
|
||||||
|
|
||||||
****Тема: Исследование контактных явлений в структуре
|
|
||||||
металл-полупроводник****
|
|
||||||
|
|
||||||
****Вариант 14,6,3****
|
|
||||||
|
|
||||||
https://www.meme-arsenal.com/memes/4598e00877a721c55a46dc4aafb78719.jpg
|
|
||||||
|
|
||||||
------------------ -- -------------
|
|
||||||
Студент гр. 1181 Шишков Д.А.
|
|
||||||
Преподаватель Филипюк И.А
|
|
||||||
------------------ -- -------------
|
|
||||||
|
|
||||||
Санкт-Петербург
|
|
||||||
|
|
||||||
2023
|
|
||||||
|
|
||||||
Задание:
|
|
||||||
|
|
||||||
Для заданной пары металл-полупроводник оценить кинетические свойства
|
|
||||||
заданных материалов, рассчитать и построить энергетическую диаграмму и
|
|
||||||
вольт-амперную характеристику контакта в заданном диапазоне температур,
|
|
||||||
дать рекомендации по применению исследуемого контакта.
|
|
||||||
|
|
||||||
Таблица 1. Некоторые свойства металлов
|
|
||||||
|
|
||||||
<table>
|
|
||||||
<tbody>
|
|
||||||
<tr class="odd">
|
|
||||||
<td><p>No</p>
|
|
||||||
<p>ВАР.</p></td>
|
|
||||||
<td>Элемент</td>
|
|
||||||
<td>Структура</td>
|
|
||||||
<td>Атомная масса</td>
|
|
||||||
<td>Параметр решетки, Å</td>
|
|
||||||
<td>Плотность, г/см3</td>
|
|
||||||
<td>Удельное сопротивление, мкОм·см</td>
|
|
||||||
<td>Температура, К</td>
|
|
||||||
<td>Работа выхода φ, эВ</td>
|
|
||||||
<td></td>
|
|
||||||
<td></td>
|
|
||||||
</tr>
|
|
||||||
<tr class="even">
|
|
||||||
<td>Дебая (TD)</td>
|
|
||||||
<td>Ферми (TF·10<sup>-4</sup>)</td>
|
|
||||||
<td>плавления (Tпл)</td>
|
|
||||||
<td></td>
|
|
||||||
<td></td>
|
|
||||||
<td></td>
|
|
||||||
<td></td>
|
|
||||||
<td></td>
|
|
||||||
<td></td>
|
|
||||||
<td></td>
|
|
||||||
<td></td>
|
|
||||||
</tr>
|
|
||||||
<tr class="odd">
|
|
||||||
<td>14</td>
|
|
||||||
<td>Au</td>
|
|
||||||
<td>ГЦК</td>
|
|
||||||
<td>196.9</td>
|
|
||||||
<td>4.08</td>
|
|
||||||
<td>19.28</td>
|
|
||||||
<td>2.2</td>
|
|
||||||
<td>165</td>
|
|
||||||
<td>6.39</td>
|
|
||||||
<td>1337</td>
|
|
||||||
<td>4.58</td>
|
|
||||||
</tr>
|
|
||||||
</tbody>
|
|
||||||
</table>
|
|
||||||
|
|
||||||
1\) Определить класс симметрии заданных материалов, построить прямую и
|
|
||||||
обратную элементарные ячейки заданных материалов. Определить размеры
|
|
||||||
Зоны Бриллюэна в направлениях X, L, К.
|
|
||||||
|
|
||||||
Гранецентрированная Кубическая решётка
|
|
||||||
|
|
||||||
Формула симметрии: 3L~4~4L~3~6L~2~9PC
|
|
||||||
|
|
||||||
Класс симметрии: m3m
|
|
||||||
|
|
||||||
Так как формулы симметрии ГЦК и простой кубической решётки совпадают,
|
|
||||||
приведём на рис. 1-3 изображения осей, плоскостей и центра симметрии для
|
|
||||||
последнего
|
|
||||||
|
|
||||||
{width="3.4504in"
|
|
||||||
height="2.9512in"}
|
|
||||||
|
|
||||||
Рис. 1 Изображение осей симметрии кубической решётки
|
|
||||||
|
|
||||||
{width="4.5437in"
|
|
||||||
height="3.0126in"}
|
|
||||||
|
|
||||||
Рис. 2 Изображение плоскостей симметрии куба
|
|
||||||
|
|
||||||
{width="2.0882in"
|
|
||||||
height="2.4307in"}
|
|
||||||
|
|
||||||
Рис. 3 Изображение центра симметрии куба
|
|
||||||
|
|
||||||
Базисные вектора:
|
|
||||||
|
|
||||||
$$a_{1} = \begin{bmatrix}
|
|
||||||
\frac{1}{\sqrt{2}} \\
|
|
||||||
\frac{1}{\sqrt{2}} \\
|
|
||||||
0 \\
|
|
||||||
\end{bmatrix}$$, $$a_{2} = \begin{bmatrix}
|
|
||||||
\frac{1}{\sqrt{2}} \\
|
|
||||||
0 \\
|
|
||||||
\frac{1}{\sqrt{2}} \\
|
|
||||||
\end{bmatrix}$$, $$a_{3} = \begin{bmatrix}
|
|
||||||
0 \\
|
|
||||||
\frac{1}{\sqrt{2}} \\
|
|
||||||
\frac{1}{\sqrt{2}} \\
|
|
||||||
\end{bmatrix}$$, считая, что постоянная решётки = 1
|
|
||||||
|
|
||||||
Построим кристаллическую решётку по заданным векторам (рис. 4)
|
|
||||||
|
|
||||||
{width="2.6874in"
|
|
||||||
height="2.4583in"}
|
|
||||||
|
|
||||||
Рис. 4 ГЦК
|
|
||||||
|
|
||||||
Объём элементарной ячейки:
|
|
||||||
|
|
||||||
$$V = {|{\overrightarrow{a_{1}} \cdot \left\lbrack {\overrightarrow{a_{2}} \times a_{3}} \right\rbrack}|} = \frac{1}{\sqrt{2}}$$
|
|
||||||
|
|
||||||
Базисные вектора обратной решётки:
|
|
||||||
|
|
||||||
$${a_{i}^{\ast} = \frac{2\pi}{V}}\left\lbrack {a_{j} \times a_{k}} \right\rbrack,{i \neq j \neq k}$$
|
|
||||||
|
|
||||||
$$a_{1}^{\ast} = \begin{bmatrix}
|
|
||||||
{\sqrt{2}\pi} \\
|
|
||||||
{{- \sqrt{2}}\pi} \\
|
|
||||||
{{- \sqrt{2}}\pi} \\
|
|
||||||
\end{bmatrix}$$, $$a_{2}^{\ast} = \begin{bmatrix}
|
|
||||||
{{- \sqrt{2}}\pi} \\
|
|
||||||
{\sqrt{2}\pi} \\
|
|
||||||
{{- \sqrt{2}}\pi} \\
|
|
||||||
\end{bmatrix}$$, $$a_{3}^{\ast} = \begin{bmatrix}
|
|
||||||
{{- \sqrt{2}}\pi} \\
|
|
||||||
{{- \sqrt{2}}\pi} \\
|
|
||||||
{\sqrt{2}\pi} \\
|
|
||||||
\end{bmatrix}$$
|
|
||||||
|
|
||||||
Изобразим её на рис. 5
|
|
||||||
|
|
||||||
{width="4.128in"
|
|
||||||
height="3.6374in"}
|
|
||||||
|
|
||||||
Рис. 5 Обратная решётка ГЦК
|
|
||||||
|
|
||||||
Первая зона Бриллюэна (рис. 6):
|
|
||||||
|
|
||||||
{width="4.6874in"
|
|
||||||
height="2.9689in"}
|
|
||||||
|
|
||||||
Рис. 6 Первая зона Бриллюэна
|
|
||||||
|
|
||||||
Размеры зоны Бриллюэна по направлениям X, L, K:
|
|
||||||
|
|
||||||
$$X = \begin{bmatrix}
|
|
||||||
0 \\
|
|
||||||
0 \\
|
|
||||||
1 \\
|
|
||||||
\end{bmatrix}$$ - центр верхнего квадрата
|
|
||||||
|
|
||||||
$$L = \begin{bmatrix}
|
|
||||||
0.5 \\
|
|
||||||
0.5 \\
|
|
||||||
0.5 \\
|
|
||||||
\end{bmatrix}$$ - центр шестиугольника
|
|
||||||
|
|
||||||
$$K = \begin{bmatrix}
|
|
||||||
0.75 \\
|
|
||||||
0.75 \\
|
|
||||||
0 \\
|
|
||||||
\end{bmatrix}$$ - середина грани соединяющей два шестиугольника
|
|
||||||
|
|
||||||
2\) Определить концентрацию электронов для заданного металла из условия
|
|
||||||
касания зоны Бриллюэна и сферы Ферми и сделать суждение о применимости
|
|
||||||
теории свободных электронов.
|
|
||||||
|
|
||||||
В момент касания волновой вектор kф, соответствующий радиусу сферы
|
|
||||||
Ферми, равен волновому вектору kз, при котором в направлении,
|
|
||||||
перпендикулярном отражающим плоскостям, выполняется уравнение
|
|
||||||
Вульфа-Брэггов. Условия касания для двумерной модели можно записать в
|
|
||||||
виде $$k_{ф} = k_{з}$$ или, поскольку $${k = 2}\frac{\pi}{\lambda}$$, то
|
|
||||||
$$\lambda_{ф} = \lambda_{з}$$.
|
|
||||||
|
|
||||||
Объем сферы Ферми в пространстве импульсов равен
|
|
||||||
$$\frac{4}{3}\pi p_{ф}^{3}$$ , где $$p_{ф}$$ -- импульс электронов на
|
|
||||||
поверхности Ферми. С другой стороны, этот же объем равен
|
|
||||||
$$\frac{N}{2}\frac{h^{3}}{V}$$, где N -- число электронов в объеме V.
|
|
||||||
Таким образом:
|
|
||||||
|
|
||||||
$$\frac{4}{3}\pi{p_{ф}^{3} = \frac{N}{2}}\frac{h^{3}}{V}$$
|
|
||||||
|
|
||||||
Откуда находим:
|
|
||||||
|
|
||||||
$${p_{ф} = h}\left( \frac{3N}{8\pi V} \right)^{1/3}$$
|
|
||||||
|
|
||||||
Поскольку по соотношению де-Бройля $$\lambda = \frac{h}{p}$$, то
|
|
||||||
$$\lambda_{ф} = \left( \frac{8\pi V}{3N} \right)^{1/3}$$
|
|
||||||
|
|
||||||
Найдем теперь λз. Из всех граней первой зоны Бриллюэна для
|
|
||||||
гранецентрированной решетки ближе всего к началу координат находятся
|
|
||||||
грани, обусловленные отражением электронов от плоскостей {111}. Поэтому
|
|
||||||
сфера Ферми впервые коснется именно этих граней. Таким образом, для
|
|
||||||
определения условий касания сферы с первой зоной Бриллюэна необходимо
|
|
||||||
найти длину волны, при которой электроны взаимодействуют с плоскостями
|
|
||||||
{111}. Из уравнения Вульфа -- Бреггов
|
|
||||||
$${\mathit{n\lambda} = 2}d\mathit{sin\theta}$$ находим:
|
|
||||||
|
|
||||||
3
|
|
||||||
|
|
||||||
$${\lambda_{з} = 2}{d = 2}{\frac{a}{\sqrt{H^{2} + K^{2} + L^{2}}} = 2}\frac{a}{\sqrt{3}}$$
|
|
||||||
|
|
||||||
(здесь θ = 90°, так как в точке касания волновой вектор перпендикулярен
|
|
||||||
к плоскостям {111}; п = 1, так как λ--наибольшее)
|
|
||||||
|
|
||||||
Если в объеме V число атомов Na, то число элементарных ячеек будет
|
|
||||||
$$\frac{N_{a}}{4}$$, так как на одну ячейку гранецентрированной решетки
|
|
||||||
приходится четыре атома, тогда $${V = a^{3}}\frac{N_{a}}{4}$$
|
|
||||||
|
|
||||||
Откуда $$a = \left( \frac{4V}{N_{a}} \right)^{1/3}$$, следовательно
|
|
||||||
$${\lambda_{з} = \frac{2}{\sqrt{3}}}\left( \frac{4V}{N_{a}} \right)^{1/3}$$
|
|
||||||
|
|
||||||
Возводя обе части этого тождества в куб и произведя необходимые
|
|
||||||
сокращения, получаем:
|
|
||||||
|
|
||||||
$$\frac{N}{N_{a}} = \frac{\pi\sqrt{3}}{4} = 1.36$$
|
|
||||||
|
|
||||||
Список литературы:
|
|
||||||
|
|
||||||
Астанин В.В. Физика твёрдого тела
|
|
295
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Normal file
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1095
main.ipynb
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54
main.py
Normal file
@ -0,0 +1,54 @@
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# %%
|
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|
import numpy as np
|
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|
|
||||||
|
def dr(*x, p = 3):
|
||||||
|
print(np.round(x, p))
|
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|
|
||||||
|
def vol(x):
|
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|
return np.dot(x[0], np.cross(x[1], x[2]))
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|
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|
# %%
|
||||||
|
A_metal = 4.08
|
||||||
|
# a_general = np.array(((1/np.sqrt(2), 1/np.sqrt(2), 0), (1/np.sqrt(2), 0, 1/np.sqrt(2)), (0, 1/np.sqrt(2), 1/np.sqrt(2))))
|
||||||
|
a_metal = A_metal/2 * np.array(((0, 1, 1), (1, 0, 1), (1, 1, 0)))
|
||||||
|
|
||||||
|
dr(a_metal)
|
||||||
|
|
||||||
|
a = a_metal
|
||||||
|
V_metal = np.dot(a[0], np.cross(a[1], a[2]))
|
||||||
|
|
||||||
|
dr(V_metal, A_metal**3/4)
|
||||||
|
|
||||||
|
a_ = 2*np.pi/V_metal * np.array((np.cross(a[1],a[2]), np.cross(a[0], a[2]), np.cross(a[0], a[1])))
|
||||||
|
|
||||||
|
dr(a_)
|
||||||
|
|
||||||
|
dr(a_[0][0], 2*np.pi/A)
|
||||||
|
|
||||||
|
X = np.array((0, 0, 1)) * A
|
||||||
|
L = np.array((0.5, 0.5, 0.5)) * A
|
||||||
|
K = np.array((0.75, 0.75, 0)) * A
|
||||||
|
|
||||||
|
dr(X, L, K)
|
||||||
|
|
||||||
|
dr(vol(a_))
|
||||||
|
|
||||||
|
# %%
|
||||||
|
|
||||||
|
A_diel = 6.48
|
||||||
|
|
||||||
|
a_diel = a_general * A_diel
|
||||||
|
|
||||||
|
dr(a_diel)
|
||||||
|
|
||||||
|
a = a_diel
|
||||||
|
V_diel = np.dot(a[0], np.cross(a[1], a[2]))
|
||||||
|
|
||||||
|
dr(V_diel)
|
||||||
|
|
||||||
|
a_ = 2*np.pi/np.abs(V_diel) * np.array((np.cross(a[1],a[2]), np.cross(a[0], a[2]), np.cross(a[0], a[1])))
|
||||||
|
|
||||||
|
dr(a_)
|
||||||
|
# %%
|
||||||
|
a = a_general
|
||||||
|
dr(2*np.pi/(np.dot(a[0], np.cross(a[1], a[2])))*np.cross(a[1], a[2]))
|
406
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|
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|
style="font-size:0.0114801px;baseline-shift:sub;stroke-width:0.264924"
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|
style="font-size:0.0114801px;baseline-shift:sub;stroke-width:0.264924"
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xml:space="preserve"
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|
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sodipodi:role="line"
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id="tspan614-6-5"
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style="font-size:0.0176389px;stroke-width:0.264583"
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x="0.95820701"
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y="4.6853299">E<tspan
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|
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|
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|
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id="tspan10471">c</tspan> - E<tspan
|
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|
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|
id="tspan10473">g</tspan>/2 = 4.68 эВ = Ф<tspan
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|
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